It may sound like overkill, but the most effective way to ensure that a cake releases cleanly from a baking pan is to grease the pan, line it with parchment paper, and then grease and flour the parchment and pan sides. The parchment guarantees that the cake pulls away from the pan bottom completely, and a coat of grease and flour on the parchment and up the pan sides helps the batter cling and rise and ensures that the parchment pulls away from the cake bottom without removing large crumbs.
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