Alum (Aluminum Sulfate) (2024)

One of the first of the several steps that municipal water suppliers use to prepare water for distribution is getting it as clear and as particulate-free as possible. To accomplish this, the water is treated with aluminum sulfate, commonly called alum, which serves as a flocculant. Raw water often holds tiny suspended particles that are very difficult for a filter to catch. Alum causes them to clump together so that they can settle out of the water or be easily trapped by a filter.

Usually a mixture of water with 48 percent filter alum is injected into the raw incoming water at a rate of 18 to 24 parts per million. The alum promotes coagulation of fine particles which helps resolve problems of color as well a turbidity. If the process is given enough time to work and is applied properly, it not only corrects problems in the water but actually results in removing most of the aluminum used in the process.

Although concern over the safety of treating water with aluminum has often been voiced, there is no evidence that aluminum in water, whether it comes from the aluminum sulfate used in treatment or from other sources, is a health issue. Actually, most aluminum that we take in does come from other sources. One study showed that only between 0.4% and 1.0% of our lifetime intake of aluminum comes from alum used to prepare municipal water. Most aluminum intake is from aluminum that occurs naturally in foods, aluminum used in food packaging, and from products like deodorants and vaccines.

Water treatment for aluminum is normally not needed, but aluminum is easy to remove with reverse osmosis or distillation.

See also“Simple Facts about Aluminum.”

More about alum from other sources:


There are a variety of primary coagulants which can be used in a water treatment plant. One of the earliest, and still the most extensively used, is aluminum sulfate, also known as alum. Alum can be bought in liquid form with a concentration of 8.3%, or in dry form with a concentration of 17%. When alum is added to water, it reacts with the water and results in positively charged ions.

Coagulation/flocculation is a process used to remove turbidity, color, and some bacteria from water. In the flash mix chamber, chemicals are added to the water and mixed violently for less than a minute. These coagulants consist of primary coagulants and/or coagulant aids. Then, in the flocculation basin, the water is gently stirred for 30 to 45 minutes to give the chemicals time to act and to promote floc formation. The floc then settles out in the sedimentation basin.

Coagulation removes colloids and suspended solids from the water. These particles have a negative charge, so the positively charged coagulant chemicals neutralize them during coagulation. Then, during flocculation, the particles are drawn together by van der Waal's forces, forming floc. The coagulation/flocculation process is affected by pH, salts, alkalinity, turbidity, temperature, mixing, and coagulant chemicals.

Source:http://water.me.vccs.edu/courses/env110/lesson4_3.htm

Aluminum sulfate is widely used as a flocculant in water treatment plants in the United States. It is also widely available in developing countries, sold in blocks of soft white stone, and generally called alum. There are numerous ways to use alum as a flocculant, including to crush it into a powder before adding it to water, stirring and decanting or stirring the whole stone in the water for a few seconds and waiting for the solids to settle. The benefits of alum are that it is widely available, is proven to reduce turbidity, and is inexpensive. The drawback of alum is that the necessary dosage varies unpredictably. Laboratory studies have shown that alum is effective at reducing turbidity and chlorine demand3.

Source: http://www.cdc.gov/safewater/chlorination-pretreatment.html#3


Alum (Aluminum Sulfate) (2024)

FAQs

Is alum the same as aluminum sulfate? ›

Aluminium sulfate is sometimes called alum or papermaker's alum, however, the name “alum” is more commonly and properly used for any double sulfate salt with the generic formula XAl(SO4)2·12H2O, where X is a monovalent cation such as potassium or ammonium (5).

Is aluminum sulfate safe for humans? ›

Alum's toxicity to humans

Aluminum sulfate is fairly non-toxic, with acute and chronic oral LD50 both greater than 5,000mg/kg (5). However, alum can still cause irritation, burns, and respiratory issues. If inhaled, it may cause headaches, nausea, and respiratory irritations.

Is Aluminium sulphate safe in drinking water? ›

Alum sulphate is a liquid flocculent for the treatment of municipal water and waste water systems. Alum works by combining the small impurities in the water to form a floc which can then be settled & if required filtered . Nowchem Alum is suitable for use in drinking water, dams, pools and the treatment of waste water.

What is aluminium sulfate used for? ›

Aluminium sulfate is used in water purification and for chemical phosphorus removal from wastewater. It causes suspended impurities to coagulate into larger particles and then settle to the bottom of the container (or be filtered out) more easily. This process is called coagulation or flocculation.

Why is alum not recommended? ›

Alum is no longer recommended because the aluminum in this product may be unsafe to consume. stored too long will not make a quality product. harbor bacteria that may cause softening in pickles. that cause softening are concentrated in the blossom end, and discarding a thin slice will help to keep pickles firm.

Is alum good for health? ›

It was concluded that alum might help control fungal isolates and it might be helpful against infections such as oral thrush and mouth ulcers.

What are the negative effects of aluminum sulfate? ›

Substantial ingestion of aluminium sulphate causes burning in the mouth and throat, gingival necrosis, nausea, vomiting, diarrhoea, abdominal pain and, in severe cases, haemorrhagic gastritis with circulatory collapse (Gosselin et al, 1984; Royal Society of Chemistry, 1989; Meditext, 1995).

Can we drink alum water daily? ›

Yes, Alum is safe to use externally and internally. In Ayurveda, Alum is used in the form of Bhasma named Sphatika bhasma which can be taken orally to manage various diseases.

What are the health effects of Aluminium sulphate? ›

The substance is severely irritating to the eyes, respiratory tract and gastrointestinal tract. The substance is mildly irritating to the skin. A harmful concentration of airborne particles can be reached quickly when dispersed, especially if powdered. The substance may have effects on the central nervous system.

What is alum used for medically? ›

Alum (AL) is one of the astringent herbal medicines that features a strong ability to dry dampness. Upon external use, it has the effects of detoxifying and killing worms in addition to an antipruritic effects. Upon internal use, it has a hemostatic effect and can check diarrhea and dispel windphlegm.

What is the difference between aluminum and alum? ›

Aluminum is an element and alum is a sulfate salt containing two metals. Aluminum is an element on the periodic table and alum refers to the Al3+ ion. Alum is an element on the periodic table and aluminum refers to the ions it forms. Alum is.

Is aluminum sulfate safe in food? ›

Two common additives that contain aluminum include sodium aluminum phosphate and sodium aluminum sulfate — which are found in self-rising flours and cheeses as well as in cereal flours, respectively, according to the FDA. Take note that both of these additives are Generally Recognized as Safe (GRAS) by the FDA.

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